Physical and chemical properties of timber by-products from Pinus leiophylla, P. montezumae and P. pseudostrobus for a bioenergetics use

This paper describes the chemical and physical properties of Pinus leiophylla, P. montezumae and P. Pseudostrobus timber by-products (wood chips, bark and wood-bark). The physical features determined were the initial moisture content, bulk density and calorific value whereas the determined chemical characteristics were pH, inorganic compounds, inorganic compounds microanalysis, extractives, lignin, and holocellulose. Such by-products were collected in the industrial complex at the Indigenous Community of Nuevo San Juan Parangaricutiro, located in Michoacán, México. The initial moisture content of the samples varied from 33.6 to 56%, while their bulk density ranged from 0.19 to 0.31 g.cm-3. The calorific value for the wood residues of the three different species of pines varied from 17.95 to 18.93 MJ.kg-1. Regarding their chemical characteristics, barks were more acid than woods, and in general, the inorganic content was lower in woods than in barks. According to the X-ray microanalysis, the major inorganic compounds found in ash were calcium, magnesium, and potassium. No heavy metals were detected at all. For the three pine species, extractives levels in barks were higher than in woods. Also, barks contained a higher concentration of lignin than woods. The highest holocellulose content was found in wood residues rather than in barks. It is concluded then that the three pine species timber by-products present physic and chemical properties that make them suitable for the production of solid biofuel.

Performance of activated carbon obtained from pine wood and determination of its adsorption capacities of ammonia and gasoline vapors

Two types of pine wood were used to produce activated carbon (AC) by chemical activation with phosphoric acid. The yield of the activated carbon (CAs) obtained by considering the following factors in the process: species, activation temperature and impregnation ratio (R = wood mass/dissolution mass), the variables of such factors being the species Pinus pseudostrobus (Pp) and Pinus leiophylla (Pl), temperature values 400 and 500°C, and values of R (1:1, 1:2, 1:3), respectively, thus having 12 combinations. The results indicate that the best performance was in the treatment with Pp 400°C and with R = 1:1. A surface area of 790 and 801 m2.g-1 and a total pore volume of 0.312 and 0.316 cm3.g-1 were obtained for the Pp 500-2 and Pl 500-2 carbons, respectively. Likewise, the adsorption capacity of ammonia and gasoline vapors of the carbon obtained was determined.

Chemical components of the branches of six hardwood species

The biomass generated from tree pruning or derived from the forest exploitations could be susceptible to chemical use and studies on chemical composition in tree branches are scarce. Therefore, in this investigation the biomass of the branches of six hardwood species (Alnus acuminata, A. jorullensis, Quercus candicans, Q. laurina, Q. rugosa and Symplocos citrea), derived from the forest use by the indigenous community of Nuevo San Juan Parangaricutiro from Michoacan State, Mexico, were used. The chemical composition in wood and bark was determined and the tannin content was evaluated by two methods of extraction: aqueous extraction and ethanolic extraction. In general, the results obtained varied as follows: pH (4.25-5.19), ash (0.08-10.23%), total extractives (6.9-49.5%), solubility to soda (25.36-70.9%), Runkel lignin (17.64-47.33 %), holocellulose (32.74-86.51%), alpha-cellulose (30.58-61.20%), tannins (0.26-10.67% by aqueous extraction, 0.23-12.21% by ethanolic extraction). No heavy metals were detected in the ash. The bark of Quercus candicans and Q. laurina, could be used for the extraction of tannins.