WOOD RESEARCH Volume 69, Number 3, 2024
SHUYU ZHAO, FU HU, LIFEN LI, YAN CAO, HUA GAO, XIAOHUI YANG, and HAILONG XU

EVALUATION OF PROPERTIES OF WOOD PLASTIC COMPOSITES MADE FROM SEVEN TYPES OF LIGNOCELLULOSIC FIBERS

This article aims to investigate the characteristics of wood plastic composites (WPC) prepared from polyethylene (PE) reinforced with lignocellulosic fibers derived from the xylem and bark of Masson pine, fir, cypress, as well as from Moso bamboo. The surface polarity and elemental composition of fibers were determined through contact angle measurements and X-ray photoelectron spectroscopy (XPS). The lignocellulosic fiber/PE composites were manufactured through hot-pressing technique, and their water absorption, mechanical properties, and mildew resistance were evaluated. The results revealed that the surface free energy of xylem fibers was higher than that of bark fibers among the three conifer species. XPS analysis showed that the O/C ratio of bark was consistently lower than that of xylem fiber. Among the three conifers, the Masson pine bark had the lowest O/C ratio (22.25%), while its xylem fibers had the highest ratio of 41.64%. WPC made with bark fibers had better water resistance. Additionally, the composites reinforced with xylem fibers showed superior static bending strength, impact strength, and mildew-resistant properties as compared to the composites reinforced with bark fibers. WPC made from bamboo fibers exhibited the best water resistance, with a water absorption rate and thickness swelling rate of 1.83% and 1.42%, respectively. They also had the highest static bending strength, elastic modulus, and impact strength, at 41.31 MPa, 3.82 GPa, and 10.24 kJ/m2, respectively. The WPC made from fir xylem fibers showed the most effective mildew resistance, with the smallest damage (0.50)

WOOD RESEARCH Volume 66, Number 6, 2021
Zhigang Wu, Xue Deng, LIFEN LI, Liping Yu, Jie Chen, Bengang Zhang, Xuedong Xi, and Qiaoyan Zhang

Investigation the fire hazard of plywoods using a cone calorimeter

A high-efficiency fire retardant composition was prepared with dicyandiamide, phosphoric acid, boric acid, borax, urea and magnesium sulfate and it was used to process veneers which were then to prepare the plywood. Meanwhile, heat release and smoke release from combustion of plywood were tested by a cone calorimeter, including heat release rate, mass loss rate, CO yield, CO2 yield and oxygen consumption. Results showed that the plywood with this fire retardant treatment had the better flame-retardant performance and smoke suppression effect as well as the stronger char-forming capability compared to plywood without fire retardant treatment. The average heat release rate, total heat release, average effective heat of combustion, total smoke release, CO yield and oxygen consumption of the plywood with fire retardant treatment were decreased by 63.72%, 91.94%, 53.70%, 76.81%, 84.99% and 91.86%, respectively. Moreover, the fire growth index of plywood treated by fire retardant was relatively low (3.454 kW·m-2·s-1) and it took longer time to reach the peak heat release rate, accompanied with slow fire spreading. The fire performance index was relatively high (0.136 s·m2·kW-1) and it took longer time to be ignited, thus leaving a long time for escaping at fire accidents. The fire hazard of plywood with fire retardant treatment was low, and its safety level was high.

WOOD RESEARCH Volume 64, Number 6, 2019
Zhigang Wu, Sicheng Chen, Meifen Tian, LIFEN LI, Liping Yu, Xuedong Xi, Jiankun Liang, Bengang Zhang, Hong Lei, Jun Zhang, and Taian Chen

Effects of heat-treatment on bonding performance of Betula alnoides

Heat-treatment woods of Betula alnoides were prepared by using vapor as the heat-conducting medium. Effects of heat-treatment time and heat-treatment temperature on equilibrium moisture content, density, pH value, contact angle and bonding performance of Betula alnoides were discussed in this paper. The results indicated that: (1) With the increase of heat-treatment temperature, the equilibrium moisture content, density and pH value of Betula alnoides decreased gradually. (2) With the increase of heat-treatment temperature, the contact angle of Betula alnoides increased from 70.08° to about 100°, resulting in the reduction of bonding strength gradually. Bonding strength of Betula alnoides after heat-treatment was related with the used adhesive. Bonding strength of different adhesives decreased to different extents. The bonding strength of Betula alnoides wood with polyvinyl acetate (PVAC) resin was generally higher than that of melamine-urea-formaldehyde (MUF) resin. The former were 6.35-4.56 MPa, and the latter were 5.60-3.00 MPa. (3) Heat-treatment time influenced equilibrium moisture content, density, contact angle, pH value and bonding strength of Betula alnoides less than heat-treatment temperature. (4) Heat-treatment could affect strength and surface performance of Betula alnoides greatly and the processing medium should be extended.

WOOD RESEARCH Volume 65, Number 5, 2020
Liping Yu, Meifen Tian, LIFEN LI, Zhigang Wu, Sicheng Chen, Jie Chen, and Xuedong Xi

Study of nano colloidal silica sol based protectant on the prevention of masson pine

In this study, wood protectants were prepared by using manganese chloride, potassium carbonate, borax and nano colloidal silica sol. Effects of the wood protectants on decay resistance, anti-mold property and fire resistance of Pinus massoniana Lamb. were discussed. The results indicated that the optimal formula of the protectant was composed of 20% colloidal silica sol and 8% modifier (manganese chloride + potassium carbonate + borax). Under this formula, the protectant had good permeability and fluidity, accompanied with synergistic effect between colloidal silica sol and modifier. Pinus massoniana Lamb. treated by the protectant with this formula showed good decay resistance, and its mass loss rates after corrosion by Gloeophyllum trabeum and Coriolus versicolor were respectively about 21% and 19%, lower than those of the control group. This indicated that the preferred samples reached I-level decay resistance according to Chinese Forestry Industrial Standards LY/T 1283-2011. Moreover, Pinus massoniana Lamb. under this formula had good anti-mold property, manifested by 100% resistance to Aspergillus niger V. Tiegh and Trichoderma viride Pers. ex Fr. The treated Pinus massoniana Lamb. also showed good fire resistance with the oxygen indexes before and after leaching respectively at 20.45% and 13.64%, higher than those of the control group. It was concluded that the formulated protectant of this research had not only multiple functions of one dose, but also comprehensive resistances to decay, mold and fire, as well as strong leaching resistance.

WOOD RESEARCH Volume 64, Number 3, 2019
LIFEN LI, Liping Yu, Zhigang Wu, and Yingcheng Hu

Delignification of poplar wood with lactic acid-based deep eutectic solvents

A process for the delignification of poplar wood using lactic acid-based deep eutectic solvents (DESs) with different hydrogen bond acceptors (choline chloride, glycine) was studied. The effect of operational parameters on the yields of the pulps and the regenerated lignins, the chemical compositions of the pulps and the delignification extent was investigated with respect to several factors, such as the types of hydrogen bond acceptor, reaction temperature and time. The maximum delignification extent of approximately 90.4% was achieved with lactic acidcholine chloride DES at 120°C for 12 h, however only about 58.4% of lignin was removed with lactic acid-glycine DES under the same reaction condition. The structural characteristics of the pulps were subsequently investigated by Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Thermogravimetric Analysis (TGA) and compared with original wood sample and microcrystalline cellulose.