THE USE OF BORIC ACID AND ANTIMONY OXIDE AS AUXILIARY MINERALS WITH HUNTITE HYDROMAGNESITE TO IMPROVE FLAME RETARDANT PROPERTIES OF WOODDUST COMPOSITES

Boric acid, antimony oxide minerals and huntite hydromagnesite minerals were used as auxiliary minerals in wood composites to change their flammability features. Composite samples were prepared by using different ratios of sawdust, huntite, hydromagnesite, antimony and boric acid combinations. The obtained samples were characterized by scanning electron microscopy (SEM) analysis to determine the structural and morphological properties of the composites. Thermal behavior of the composites was determined by differential thermal analysis-thermogravimetry (DTA-TG). Tensile and three-point bending tests were performed to understand the mechanical properties. Finally, the flame retardant performance of the samples was observed according to UL94 vertical flammability tests. It was concluded that wood composites containing inorganic minerals gained resistance against fire, a good synergistic effect was obtained in different additive types

A synergic effect of water-based acrylic resin with boric acid on leachability

In this study, the Scots pine wood samples were impregnated (single treatment) with boric acid combined with two types of water-based acrylic resin (pure acrylic and semi-translucent acrylic emulsion) to limit the boron leaching and improve the decay resistance. The results showed dimensional stability in anti-swelling efficiency and water absorption improved in wood specimens treated with boric acid and acrylic types. While the leachability was over 90% for only 3% boric acid-impregnated wood (control), it was calculated at 36% for acrylic emulsions-impregnated wood. Although there were no weight losses for the unleached woods, it was up to 9% for leached woods impregnated with acrylic resin and emulsion. The 25% acrylic emulsion had no weight losses after the leaching test for Coniophora puteana and Trametes versicolor. The boric acid combined with acrylic resin can improve the leaching resistance with the synergic effect, enhancing resistance against biological threats.

Determination of some properties of Scotch pine (Pinus sylvestris L.) wood which is impregnated with boron compounds and quechua

As the industrialisation and technological developments increase; the search for functional material which is environment-friendly, non-toxic, flame resistant, with a broad applicability and with high-temperature endurance also increases. Even though the wood material corresponds most of these features, its possession of an organic structure causes it to be affected negatively by damages occurring under proper conditions in the outdoor environment. Due to this reason, this study is conducted to prevent damages (biotic, abiotic pests, fire, etc.) caused by the environment to the wooden material, and to determine some physical and mechanical properties of wooden material impregnated with quechua, borax and boric acid, which are used to extend the usage life. Those features are needed in an outdoor environment. The Scotch pine (Pinus sylvestris L.) test specimens are prepared with borax, boric acid, borax+boric acid, from borax compounds, which have a great potential in Turkey, and with quechua, one of the natural impregnation substances. Then these samples are impregnated with three different (1%, 3%, 5%) solution concentrations according to ASTM 1413-76 standards and some physical-mechanical property changes are investigated. After impregnation, samples are tested and compared with control samples. According to the test results; the lowest oven dried density change is obtained in borax as 0.46 g.cm-3 in terms of boron compounds and the retention amount is determined to be highest with 3.83 kg.m-3 in the samples impregnated with boric acid. The bending strength and elastic modulus are found to be highest with 83.53 MPa and 10281 MPa in the samples impregnated with boric acid. When examined at the concentration level, it is determined to be highest with 81.89 MPa in samples with 3% concentration. There are statistical discrepancies with 55.77 MPa in the comprehensive strength parallel to grain in boric acid in terms of boron compounds.