Chemical characteristics of Eucalyptus pellita with heart rot

Eucalyptus pellita has been posited as a primary raw material in Indonesia due to its fast growth. In some areas, however, trees with heart rot were found. Thus, the wood with heart rot was analysed chemically both in sound (sapwood, outer heartwood, inner heartwood) and degraded parts (heart rot-affected wood/HRAW). The results revealed that there was a different trend in the wood chemical composition between bottom and centre parts. In bottom parts, wood with bigger diameter of heart rot, the slight changes in polysaccharides and lignin amounts was observed in HRAW compared to sound wood parts. On the contrary, comparatively high lignin and low polysaccharide levels in HRAW were measured in centre parts. HRAW was also characterized with high content of inorganic materials and high pH values but low in extractive content, mostly ethanol soluble extractives or its polar fraction. Increasing of phenolic contents was more pronounced in HRAW of lower part than that of upper of the stem. The difference trend of chemical composition between bottom and centre parts suggesting the cause of heart rot could be several wood degraders.

Study on color and surface chemical properties of Eucalyptus pellita wood subjected to thermo-vacuum treatment

The objective of this study was to investigate the color and surface chemical properties of Eucalyptus pellita wood subjected to thermo-vacuum treatment. Specimens were thermally modified in a vacuum at various temperatures for 4 h. The color parameters of untreated and heattreated samples were measured using the CIE Lab method. Surface chemical properties were evaluated by UV-Vis spectroscopy, 13C NMR spectroscopy and X-ray photoelectron spectroscopy. The results showed that eucalypt wood became darker uniformly throughout with the increase of treatment temperature, and the total color variation ΔE* obviously increased at higher temperature. The spectral changes indicated that degradation and oxidation of hemicellulose, lignin and extractives contributed to the formation of color substances during thermo-vacuum treatment. Crystalline content of carbohydrates increased. The decrease in O/C ratio signified the increase of the relative content of lignin and extractives on the wood surfaces in the heating process.