Study of wood adhesives on the bonding properties in solid and hollow glulam beams of Pinus radiata

The aim of this research was study of polyurethane (PUR), isocyanate polymer emulsions (EPI) and melamine-urea-formaldehyde (MUF) adhesives, on the bonding properties of solid and hollow glulam beams of Pinus radiata. The thermomechanical analysis (DMA) of the adhesives was carried out to evaluate their stiffness and reactivity. Glulam beams were evaluated by a bending test. The quality of the bonding was evaluated by resistance to shear and delamination. The morphology of the bonding was studied by microscopy. The DMA study showed that the MUF adhesive had the highest level of stiffness and reactivity. The results of the bending test showed that the highest modulus of rupture results were obtained in solid and hollow laminated beams with MUF adhesive, achieving increases of 30% over the PUR adhesive. The lowest delamination results were obtained in solid glulam beams with MUF and EPI adhesives, while the highest results were 32% and 47% for the PUR adhesive. Finally, glulam beams manufactured with MUF adhesive presented the best performance and results.

Study on concentrations of acids and alcohols emitted by pinus radiata during high-temperature drying

The purpose of this paper is to investigate the influence of kiln temperature, relative humidity and wood moisture content on the content of acid and alcohol released in the drying process of high temperature kiln by studying the radiated pine sawn timber of 40mm thickness. The drying temperature was between 101°C and 115°C, the relative humidity in the drying kiln was reduced from 86.1% to 39.6%, the moisture content of the lumber was reduced from 106.16% to 11.98%, and gas extraction was executed nine times with an extraction speed of 1.0 L•min-1 and a sampling time of 30 min. The concentrations of acids and alcohols were analyzed by HPLC. The results showed that the concentrations of formic acid, acetic acid, and methanol emitted in the kiln during drying were 215.6-748.2, 4148.8-16803.2, and 6381.9-15648.9 mg•m-3, respectively, and these concentrations were significantly higher than the relevant standards. The concentrations of the emitted formic acid and acetic acid were proportional to the drying temperature, the concentrations of the emitted formic acid and acetic acid were inversely proportional to the relative humidity in the kiln and the moisture content of the lumber. The concentration of the emitted methanol was independent of the drying temperature, relative humidity in the kiln, and moisture content of the lumber. It is therefore suggested that formic acid, acetic acid, and methanol be separately recovered during the high-temperature drying of Pinus radiata lumber.