Physical and chemical properties of timber by-products from Pinus leiophylla, P. montezumae and P. pseudostrobus for a bioenergetics use

This paper describes the chemical and physical properties of Pinus leiophylla, P. montezumae and P. Pseudostrobus timber by-products (wood chips, bark and wood-bark). The physical features determined were the initial moisture content, bulk density and calorific value whereas the determined chemical characteristics were pH, inorganic compounds, inorganic compounds microanalysis, extractives, lignin, and holocellulose. Such by-products were collected in the industrial complex at the Indigenous Community of Nuevo San Juan Parangaricutiro, located in Michoacán, México. The initial moisture content of the samples varied from 33.6 to 56%, while their bulk density ranged from 0.19 to 0.31 g.cm-3. The calorific value for the wood residues of the three different species of pines varied from 17.95 to 18.93 MJ.kg-1. Regarding their chemical characteristics, barks were more acid than woods, and in general, the inorganic content was lower in woods than in barks. According to the X-ray microanalysis, the major inorganic compounds found in ash were calcium, magnesium, and potassium. No heavy metals were detected at all. For the three pine species, extractives levels in barks were higher than in woods. Also, barks contained a higher concentration of lignin than woods. The highest holocellulose content was found in wood residues rather than in barks. It is concluded then that the three pine species timber by-products present physic and chemical properties that make them suitable for the production of solid biofuel.

Chemical components of the branches of six hardwood species

The biomass generated from tree pruning or derived from the forest exploitations could be susceptible to chemical use and studies on chemical composition in tree branches are scarce. Therefore, in this investigation the biomass of the branches of six hardwood species (Alnus acuminata, A. jorullensis, Quercus candicans, Q. laurina, Q. rugosa and Symplocos citrea), derived from the forest use by the indigenous community of Nuevo San Juan Parangaricutiro from Michoacan State, Mexico, were used. The chemical composition in wood and bark was determined and the tannin content was evaluated by two methods of extraction: aqueous extraction and ethanolic extraction. In general, the results obtained varied as follows: pH (4.25-5.19), ash (0.08-10.23%), total extractives (6.9-49.5%), solubility to soda (25.36-70.9%), Runkel lignin (17.64-47.33 %), holocellulose (32.74-86.51%), alpha-cellulose (30.58-61.20%), tannins (0.26-10.67% by aqueous extraction, 0.23-12.21% by ethanolic extraction). No heavy metals were detected in the ash. The bark of Quercus candicans and Q. laurina, could be used for the extraction of tannins.

Chemical characteristics of Eucalyptus pellita with heart rot

Eucalyptus pellita has been posited as a primary raw material in Indonesia due to its fast growth. In some areas, however, trees with heart rot were found. Thus, the wood with heart rot was analysed chemically both in sound (sapwood, outer heartwood, inner heartwood) and degraded parts (heart rot-affected wood/HRAW). The results revealed that there was a different trend in the wood chemical composition between bottom and centre parts. In bottom parts, wood with bigger diameter of heart rot, the slight changes in polysaccharides and lignin amounts was observed in HRAW compared to sound wood parts. On the contrary, comparatively high lignin and low polysaccharide levels in HRAW were measured in centre parts. HRAW was also characterized with high content of inorganic materials and high pH values but low in extractive content, mostly ethanol soluble extractives or its polar fraction. Increasing of phenolic contents was more pronounced in HRAW of lower part than that of upper of the stem. The difference trend of chemical composition between bottom and centre parts suggesting the cause of heart rot could be several wood degraders.